Learn vocabulary, terms, and more with flashcards, games, and other study tools. The bigger the ions, the more distance there is between their centres, and the weaker the forces holding them together. Lattice enthalpy is the energy released when one mole of a compound is formed from its constituent gaseous ions under standard conditions. Is this a homework question or a curiosity question? For Group 2, magnesium sulphate is soluble while strontium and barium sulphates are insoluble. 9000 ft.) is 15,000 feet high? Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. If two ions of different sizes were surrounded by an equal number of water molecules each, the smaller ion would be more hydrated compared to the larger one due to the size differential. Problems with the usual explanations "Rubato sufficiently repeated turns into a feature of the rhythm." This page discusses the solubility of the hydroxides, sulfates and carbonates of the Group 2 elements—beryllium, magnesium, calcium, strontium and barium—in water. About a week ago I was playing around with some DH, lattice energy, and Ksp data and I found that barium seems to go against the "trend". The Student Room, Get Revising and Marked by Teachers are trading names of The Student Room Group Ltd. Register Number: 04666380 (England and Wales), VAT No. Making statements based on opinion; back them up with references or personal experience. $F\propto 1/r^{2}$. Lattice enthalpy is dependent on the length of the ionic bond between the cation and the anion in the compound. While progressing down Group 2, the size of the cation increases since the number of shells increases to accommodate to the extra electrons. John W. Lv 7. A shorter bond would require more heat energy to be broken. Let's deal with $\ce{OH-}$ first. If the latter, do you know that barium salts tend to go against the "trend"? Are broiler chickens injected with hormones in their left legs? Why should I expect that black moves Rxd2 after I move Bxe3 in this puzzle? SOLUBILITY OF THE HYDROXIDES, SULPHATES AND CARBONATES OF THE GROUP 2 ELEMENTS IN WATER. (Start typing, we will pick a forum for you), Taking a break or withdrawing from your course, Maths, science and technology academic help, Trend in Solubilities of Group 2 Sulfates. Why do people call an n-sided die a "d-n"? Can someone explain the solubility of Group 2 compounds in a better way? WJEC Chemistry. Stack Exchange network consists of 176 Q&A communities including Stack Overflow, the largest, most trusted online community for developers to learn, share their knowledge, and build their careers. Sulfates Group 2 sulfates become less soluble down the group. site design / logo © 2020 Stack Exchange Inc; user contributions licensed under cc by-sa. chemguideforcie.co.uk/2016section10/learning10p1g.html, http://www.chemguide.co.uk/inorganic/group2/solubility.html, MAINTENANCE WARNING: Possible downtime early morning Dec 2/4/9 UTC (8:30PM…, “Question closed” notifications experiment results and graduation. Although it describes the trends, there isn't any attempt to explain them on this page - for … The hydration enthalpy also decreases since the size of the cation increases. I have heard this "trend" explained in this way: Hydroxide is hard and sulfate is soft. Since the hydration enthalpy decreases faster than the lattice enthalpy in the case of Group 2 sulphates, the solubility of Group 2 sulphates decreases while progressing down the group. Reactivity of alkaline earth metals towards water, Apparent contradiction in the name of group 2 elements. GCSE. why is the melting point of calcium sulfate high, Doubt about the trends of entropy for hydration of ions, IAL Physics and Chemistry revision songs, MK II, Ial chemistry unit 3 may 2018 send ur Answers here.